
Spontaneity and nature of attack of fluorine gas on aluminum
Apr 13, 2021 · Fluorine is one of the most dangerous substances out there, and one of the presumed products, $\ce{OF2}$, is also terrifying. If you can calculate the free energy change for a reaction, you will know whether it is spontaneous.
inorganic chemistry - Why is fluorine the most electronegative …
Feb 27, 2014 · Fluorine has a high electron affinity (easy to gain an electron) and a high ionization energy (hard to lose an electron). There are other scales, including the Allred-Rochow scale , based on effective nuclear charge and covalent radius , the Sanderson scale based on atomic size, and the Allen scale based on the average energy of the valence ...
Is F2 two fluoride ions or just one? - Chemistry Stack Exchange
May 22, 2015 · A fluorine atom can share electrons with another nonmetal to form a covalent bond. When sharing electrons in a covalent bond, the fluorine is still called an atom, because it has not gained complete control over the electron that is completing its $2p$ orbital. In the $\ce{F2}$ molecule, there are to fluorine atoms.
halides - Can fluorine ever have a positive oxidation state ...
May 5, 2021 · Rather, the gold is bonded octahedrally to five individual fluorine atoms and a difluorine ($\ce{F2}$) ligand, the latter attached end on and rotated so that in the most stable conformation (according to most of the several optimization schemes used), the remote fluorine atom is eclipsed with one of the other ligands as if attracted to it (a ...
Is it possible to burn things in a halogen atmosphere?
Jun 8, 2019 · Fluorine gas definitely supports flaming combustion. And does so more than oxygen. Very dramatic, actually. Chlorine, less so than oxygen or air, but still possible in right setting. See below for examples of fluorine flames. Examples are not in $100~\%\ \ce{F2}$ environment, but should be obvious that $\ce{F2}$ makes more flames than air. In ...
organic chemistry - Why are fluorides more reactive in nucleophilic ...
Jul 25, 2013 · I guess it's conceivable that the presence of fluorine atoms would better stabilize the Meisenheimer complex than other halogens, though I don't know for sure. Still, since all halogens are electron-withdrawing by induction or negative hyperconjugation, the presence of more strongly electron-withdrawing groups (e.g., nitro) conjugated to the ...
Why does chlorine have a higher electron affinity than fluorine?
Nov 12, 2013 · Fluorine, though higher than chlorine in the periodic table, has a very small atomic size. This makes the fluoride anion so formed unstable (highly reactive) due to a very high charge/mass ratio. Also, fluorine has no d-orbitals, which limits its atomic size. As a result, fluorine has an electron affinity less than that of chlorine.
halides - Why is fluorine more reactive than iodine despite the …
In comparing the reactivity of fluorine or iodine, there are a couple of factors to consider. Part of it is the strength of the $\ce{X–X}$ bond, which is a barrier that tends to discourage them from reacting. Obviously, the higher this barrier, the less reactive the halogen is (in general).
polarity - What determines "polarizability" of an element?
Jun 29, 2017 · The very uneven electron distribution of the iodine atom causes the hydrogen-iodine bond to be slightly unstable. On the contrary, since there is not so much of polarisation within the fluorine atom and thus, the hydrogen-fluorine bond is much more stable. However, that is not the most important explanation for the bond strength to be as such.
Why only F, O and N form Hydrogen Bonds? [duplicate]
Apr 27, 2018 · No, that's not necessary. Amongst the strongest hydrogen bonds are formed by $\ce{ N, O, F}$ because of their high electronegativity.